尹强兵, 陈爱宏, 陈浩川, 林奕嘉, 彭志敏, 王欣. 2011—2017年深圳某区珠宝首饰加工行业天那水挥发性化学组分分析[J]. 职业卫生与应急救援, 2018, 36(6): 512-516. DOI: 10.16369/j.oher.issn.1007-1326.2018.06.009
引用本文: 尹强兵, 陈爱宏, 陈浩川, 林奕嘉, 彭志敏, 王欣. 2011—2017年深圳某区珠宝首饰加工行业天那水挥发性化学组分分析[J]. 职业卫生与应急救援, 2018, 36(6): 512-516. DOI: 10.16369/j.oher.issn.1007-1326.2018.06.009
YIN Qiangbing, CHEN Aihong, CHEN Haochuan, LIN Yijia, PENG Zhimin, WANG Xin. Analysis of volatile chemical compositions of thinner used in jewelry processing industry during 2011 to 2017 in Luohu Disrtict[J]. Occupational Health and Emergency Rescue, 2018, 36(6): 512-516. DOI: 10.16369/j.oher.issn.1007-1326.2018.06.009
Citation: YIN Qiangbing, CHEN Aihong, CHEN Haochuan, LIN Yijia, PENG Zhimin, WANG Xin. Analysis of volatile chemical compositions of thinner used in jewelry processing industry during 2011 to 2017 in Luohu Disrtict[J]. Occupational Health and Emergency Rescue, 2018, 36(6): 512-516. DOI: 10.16369/j.oher.issn.1007-1326.2018.06.009

2011—2017年深圳某区珠宝首饰加工行业天那水挥发性化学组分分析

Analysis of volatile chemical compositions of thinner used in jewelry processing industry during 2011 to 2017 in Luohu Disrtict

  • 摘要:
    目的 分析珠宝首饰加工行业天那水挥发性化学组分, 为有效开展珠宝首饰加工行业职业病危害因素监测与职业病防治工作提供参考。
    方法 运用气相色谱-质谱联用仪, 对从63家珠宝首饰加工企业收集到的64份天那水样品进行挥发性化学组分检测, 并对结果进行汇总分析, 对作业现场进行职业卫生学调查。
    结果 64份天那水样品中, 共检出56种挥发性化学组分, 检出率前两位的是二氯甲烷、甲醇, 其检出率分别为67.19%、53.13%, 此外还检出了苯、甲苯、二甲氧基甲烷、戊烷、氯甲烷、丙醇、己烷(其他异构体)、二甲基环戊烷等化学物质。挥发性化学组分在64份样品中体积分数均值最高的前三种物质为二氯甲烷(33.91%)、甲醇(7.9%)和苯(7.1%)。检测出的高风险挥发性化学组分有三氯乙烯、正己烷、1, 2-二氯乙烷和苯。检出挥发性化学组分最多的一份样品含有11种组分。珠宝首饰加工行业天那水月使用量为0.5~18.0 kg; 岗位的卫生工程防护设施配备率较高, 超90%, 但个体防护用品的配备率较低, 仅21.9%。
    结论 从珠宝首饰加工行业天那水挥发性化学组分职业病危害因素的数量、含量、毒理性质等方面综合分析, 珠宝首饰加工行业使用的天那水中存在的职业病危害因素应当引起职业卫生监管部门和企业的重视。

     

    Abstract:
    Objective To analyze the volatile chemical compositions of thinner used in jewelry processing industry, and to provide evidence for occupational hazards monitoring and prevention of occupational diseases in jewelry processing industry.
    Methods Totally 64 thinner specimens sampled from 63 jewelry processing enterprises were analyzed by gas chromatography and mass spectrometry, and the results were statistically analyzed. Occupational health field investigation was done while the thinner samples were taken.
    Results Among 64 samples, 56 volatile chemical compositions were detected. The top two of detection rates were dichloromethane and methanol, and the detection rates were 67.19% and 53.13%, respectively. Other chemical compositions were benzene, methylbenzene, dimethoxymethane, pentane, methyl chloride, propyl alcohol, pexane(other isomers), dimethylcyclopentane, and so on.The first three compounds with the highest mean volume fraction of volatile chemical components in 64 samples were dichloromethane(33.91%), methanol(7.9%) and benzene(7.1%). The detected volatile chemical components with high risk included trichloroethylene, hexane, 1, 2-dichloroethane and benzene. It was noted that the sample with the most volatile chemical components detected contained 11 components. The field survey showed that the monthly usage of thinner in jewelry processing industry was 0.5-18.0 kg, and the rate of equipping engineering protective facilities was higher than 90%, but the rate of using individual protective equipment was only 21.9%.
    Conclusion Considering the quantity of the detected occupational hazards of volatile chemical components of thinner and their proportion and toxicity, occupational health supervision departments and enterprises should pay more attention to such occupational hazards in thinner used in Jewelry processing industry.

     

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