Abstract: Rongalite are easy to spontaneous decompose,or decompose when meet water. In the process of its manufacture,storage,transportation and marketing,it is easy to cause accident,resulting in casualties and serious environmental pollution under mismanagement condition. Rongalite fire accidents often bring sudden,mass,fast and lethal disasters. The improper disposal may cause great losses. In order to avoid similar accidents,the experience on fire fighting against the rongalite fire in a chemical engineering company limited of Liuhua Group in Zhuzhou City is introduced and discussed,and the preventive measures are present.